Characteristic x-rays

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  • Characteristic x-rays result from Coulomb interactions between the incident electrons and atomic orbital electrons of the target material (collisional loss).
  • In a given Coulomb interaction between the incident electron and an orbital electron, the orbital electron is ejected from its shell and the resulting orbital vacancy is filled by an electron from a higher level shell.
  • The energy difference between the two shells is:
    • Either emitted from the target atom in the form of a photon referred to as characteristic photon.
    • Or transferred to another orbital electron that is ejected from the target atom as an Auger electron.


Characteristic photon and Auger electron eKLM following a vacancy in the atomic K shell.
Characteristic photon and Auger electron eKLM following a vacancy in the atomic K shell.
  • Characteristic photon and Auger electron eKLM following a vacancy in the atomic K shell.
    • Energy of K photon: NEED TO UPLOAD IMAGES AND INSERT Slide 15
    • Energy of eKLM Auger electron:NEED TO UPLOAD IMAGES AND INSERT Slide 15


  • The fluorescent yield ω gives the number of fluorescent (characteristic) photons emitted per vacancy in a shell ( 0 ≤ ω ≤ 1) and ranges from 0 for low Z atoms through 0.5 for copper (Z = 29) to 0.96 for high Z atoms for K-shell vacancies that are the most prominent sources of characteristic x-rays.
  • The photons emitted through electronic shell transitions have discrete energies that are characteristic of the particular target atom in which the transitions have occurred; hence the term characteristic radiation.
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